Microwave spectrum and structure of the dimethylamine dimer: Evidence for a cyclic structure
نویسندگان
چکیده
Rotational spectra have been measured for six isotopomers of the dimethylamine dimer using a Fourier-transform microwave spectrometer. No tunneling splittings were observed for either the aor c-type rotational transitions and the spectra could be fit to a rigid rotor Hamiltonian including centrifugal distortion terms. Possible dimer structures are discussed and compared to the experimentally determined moments of inertia, dipole moments, and nuclear quadrupole coupling constants. A cyclic structure with C, symmetry was found to best reproduce the inertial data. The structure of the dimethylamine dimer is compared to the theoretical and experimental structures for the ammonia dimer.
منابع مشابه
G-protein Coupled Receptor Dimerization
A growing body of evidence suggests that GPCRs exist and function as dimers or higher oligomers. The evidence for GPCR dimerization comes from biochemical, biophysical and functional studies. In addition, researchers have shown the occurrence of heterodimerization between different members of the GPCR family. Two receptors can interact with each other to make a dimer through their extracellular...
متن کاملStructural, optical and dielectric studies in ZnO nanorods by microwave assisted method
ZnO nanorod was prepared by microwave assisted method. The crystal structure of the nano powders were confirmed by X-Ray diffraction analysis and the mean particle size was estimated by the Scherrer,s formula .The surface morphology of the nano particles were analyzed by using SEM . The absorption spectrum of the material in the UV-Vis range was recorded .The energy band gap of the...
متن کاملStructural, optical and dielectric studies in ZnO nanorods by microwave assisted method
ZnO nanorod was prepared by microwave assisted method. The crystal structure of the nano powders were confirmed by X-Ray diffraction analysis and the mean particle size was estimated by the Scherrer,s formula .The surface morphology of the nano particles were analyzed by using SEM . The absorption spectrum of the material in the UV-Vis range was recorded .The energy band gap of the...
متن کاملTHE ROLE OF AMINES AS TEMPLATES IN DIRECTING THE STRUCTURE OF ZEOLITES
In this article, we have investigated the role of dimethylamine (DMA), tributylamine (TBA), Triethanoleamine (TEA), Trishydroxymethylamine (TRIZMA), and Hexamethyleneterraamine (HMTA), in the formation of zeolitic compounds. The experiments were carried out in acidic and basic media using Si/Al< 10 and Si/A1>10. The structure of the resulting synthetic zeolites were similar to Natro Davyne,...
متن کاملDesign, Fabrication and Measurement of Two-Layered Quadruple-Band Microwave Metamaterial Absorber
The design, simulation, fabrication, and measurement of two structures of metamaterial absorbers (MA) is investigated at microwave frequency in this paper. By stacking of one layer structure on the top of each other, a two-layered structure is generated. The unit cell at each layer consisting of two sets of various circular and square patches are designed so that the structure exhibit quad band...
متن کامل